The interaction of electromagnetic radiations
with the atoms is a wave-particle interaction. The interaction is mainly based
on the specified absorption and energy is absorbed based on radiations and
discrete packages of energy that are quanta and photons. The absorbance of
light in the materials depends on the atomic structures and atomic orbital
configurations. The occupied orbitals in the atoms are finite and well defined
but still, the motion of electrons is not restricted in the energetic orbitals (Skoog, et al., 2007).
The electrons of material absorb energy and
come to excited states that are unstable states. The electrons in the excited
states come back to the ground state and radiate energy that is emission. Based
on atomic structures of the materials the appropriate radiation effect can be
demonstrated. The electrons are excited in the outer most shell and through
transition process reaches to the higher energy levels and corresponds to the
shorter wavelength of the radiation.
Figure 3:
Electromagnetic spectrum of light

Reference
of A mixture of absorbing substances
Skoog, D. A., Holler, F. J. & Crouch, S. R., 2007.
Principles of Instrumental Analysis. In: s.l.:Thomson Brooks/Cole, p. 1039.