Many of the people are not well
aware of the word Olefin. Here is some of the basic information regarding
Olefin that can help in the better understanding of this word. Olefin is also
known as Alkene, it is a compound which is made up of carbon as well as hydrogen
that can contain only one or more than pairs of the carbon atoms which are
linked through a double bond. Olefins are the examples of the hydrocarbons
which are in the unsaturated form.
There are oil refineries that are
responsible for the production of olefins and aromatics through a process of
fluid catalytic cracking of petroleum. There are many of the chemical plants
which produce olefins through the catalytic reforming of Naphtha. Ethylene is
produces from a mixture of propane through a steam cracking process which is
further divided into three main steps to make it purified.
Quenching and Cracking of Olefins Production
This is the very first step which
initiates the process in which a mixture made up of ethane-propane is fed into
a long vessel type of part which is called as a furnace. In the furnace
temperature is maintained and is very high. After putting the mixture in a
furnace under severe conditions, mixture gets cracked and the products which
obtained are ethylene, propylene and many other byproducts as well. Furnace
outlet in which mixture gets poured is subsequently being fed to the
water-based quench. The furnace is being put into the water system to make sure
that no further reaction takes place in the furnace and the production of
undesirable products don’t take place.
After this, from the quench tower
different heavy, condensed steam, coke and tar are being removed. Cracked gas
is then further directed to the next compression step from the quench.
Drying and Compression of Olefins Production
This is the second step of the
cracking process in which cracked gas sent from quench is then gets compressed
across the five different stages. In first two stages cracked gas only gets
compressed while after the third stage, sulfur and carbon dioxide gets removed
from the cracked gas which was compressed as well through the use of water and
caustic soda in a caustic scrubber. After this method, the compressed cracked
gas gets cooled down and then subsequently gets dried with the help of
molecular sieves which are responsible for the removing of most of the excess
water from the gas which has been come along during the process of compression.
Separation of Olefins Production
This is the last and most
important step in the whole process. This step is not just composed of one
technique like the others but have many different parts in it. In this step,
dried cracked gas is being transferred to the cold box so that hydrogen and the
light hydrocarbons get removed through doing this from a cracked gas. This
method is also being used to make sure that along with the other hydrocarbons,
ethylene doesn’t gets out of the gas.
Now on this point, different
condensates from the train of chilling are further fed to the series of separation
compartments. In the very first compartment also known as demethanizer, then
the methane is being collected from the top which is then further used into a
chilling box and the bottom stream is then fed to the second compartment also
termed as deethanizer.
Top part of the deethanizer is
primarily composed of ethane and ethylene which is then fed towards the
converter known as acetylene and then further gets fractionated into the C2
splitter. In this compartment or column, lights are being removed from the
overhead and then gets recycled to the system known as compression. While the
polymer grade ethylene is taken from the column just like as side stream.
Ethane gets recycled to the cracking furnaces from the bottoms of C2 splitters.
Afterwards the bottom of
deethanizer is further fed to the depropanizer which is being used for the
distilling of C3 compartments into the overheads. The overhead is a stream
which is hydro treated catalytically for the methyl acetylene and for the
removal of propdiene. After this, they are being fed to the C3 splitter. In
this compartment, lights get removed from the overheads and are further
recycled to the compressors. Polymer grade propylene is also drawn from the
long column but as a side stream. Propane which was obtained from the C3
splitter bottom gets recycled towards the cracking furnace.
Different parts of the apparatus are of Olefins Production
Long Furnaces with a set high
temperature.
Quench column which was used in
the first step.
Compression system to make sure
that cracked gas is compressed properly in the second step.
Caustic scrubber which was also
used in the second step along with the use of water and caustic soda.
Drying unit to make sure that the
gas has no water vapors in it or else the process can get failed.
Cold box or chilling box for the
removing of hydrocarbons from the gas.
Demethanizer and Deethanizer
columns or compartments.
C2 and C3-spliters.
Cooling tower.
Economic performance of the cracking process of Olefins Production
Before two years back into 2015,
economic performance of this whole method was evaluated which showed that
almost 1,700,000 ton every year ethylene is being constructed through this
method. Expenses are also very much as it is a very large process and at a time
small amount of the ethylene can’t be produces but it is being produced in the
tons so this whole method costs a really big amount which is being neglected
due to a reason that olefin is being used in the number of different products
without which we can’t consider our life easy and happy. if we reduce its
construction than it can make a big problem.
Global View of Olefins Production
Olefin is one of the major
petrochemicals that is being produced in the whole world if we look at its
percentage among others. Through the production of ethylene from this process
many major chemicals are also being produced through its help which are
polyethylene, ethylene oxide and the list goes on and on. So it does not only
play its part in the factories but also in the production of many other
chemicals as well which are as useful as olefin itself. Along with this if we
go out from the industries, this is a petrochemical which is being used in the
number of other products manufacturing as well.
Applications of Olefins Production
Olefin for the very first time
was manufactured into 1950’s. It has number of applications not just in the
industries but in the household accessories as well. Now let’s have a look that
how when and where Olefins are being used:
This product is being used in the
manufacturing of different products.
Different household products are
being made with the help of the Olefins.
Color of clothes are obtained
from the Olefins, in short they are used in the manufacturing of dyes.
Another application of olefins is
the cross Metathesis in the synthesis of Natural products.
It also acts as a plastomers with
a density of almost 0.9 and index of 1.0 melt. They are excellent for the
roofing applications.
Through olefin metathesis
catalytic transformation of seed oil also takes place.
One of the most important
application is in the field of petrochemicals. They help in the conversion
technology.
Olefin is the one which is highly
resistant towards the deterioration from the moisture and chemicals. It also
has one drawback in it that it has very low melting point due to which it is
inflammable and will definitely get melted when it will be exposed to the high
heat.
Materials which help to make
olefin are very efficient due to which olefin is highly recommended for
packaging and active usage as well.
Olefins were not very successful
at the start but then in the 1960’s their usage was increased and it started to
gain the popularity with every passing year. There is a very resistant and
strong global economy that has continued it demand for the growth of light
olefins.
Cons of Olefins Production
No doubt there are many of the
applications where olefins are being used but if we look it deep inside there
are cons as well and every product or petrochemical do have so let’s talk about
them what are the things or points that makes this olefin petrochemical not
good in its use.
It is not a resilient fiber at
all. When any pressure or damage takes place to it doesn’t comes back to its
original shape that easily. Area where pressure gets on it they lie down and
special effort requires to being back in shape. In the furniture such marks can
remain permanent for the owner.
It is one of the most sensitive
fiber among the others. It can easily melt down. No doubt that its melting
point is 300 degrees but it starts melting before this temperature and
therefore it is not being used at the areas where there are chances that
temperature might get high.
It is a petrochemical that can
easily get destroyed or damaged by Friction. Just through dragging a heavy
piece on the products made up of olefin can cause them to have permanent marks
due to the heat which gets generated through friction.
It is a chemical from which roofs
are being made but it is not stain resistant. Any stain which appears on the
roofs or walls made from the olefin don’t gets away and remain on it forever.
It has very low rate of
absorbency due to which it is a very difficult task to dye it. Therefore it is
often seen to have dyed with different colors in the market but these colors
are restricted ones.
References of Olefins Production
[1]
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R. Kohen and A.
Nyska, "Oxidation of biological systems: oxidative stress phenomona,
antioxidants, redox reactions, and methods for quantification," Toxicologic
pathology, pp. 620-650, 2002.
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[2]
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E. A. Katsman, V. Y.
Danyushevsky, P. S. Kuznetsov, R. S. Shamsiev and A. S. Berenblyum,
"Kinetics and mechanism of the production of higher olefins from stearic
acid in the presence of an alumina-supported nickel sulfide catalyst," Kinetics
and Catalysis, pp. 147-155, 2017.
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[3]
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M. Inaba, K. Murata,
I. Takahara and K.-i. Inoue, "Production of Olefins and Propylene from
Ethanol by Zr-Modified H-ZSM-5 Zeolite Catalysts," Advances in
Materials Science and Engineering, pp. 1-7, 2012.
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[4]
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N. Zhang, D. Mao and
X. Zhai, "Selective conversion of bio-ethanol to propene over
nano-HZSM-5 zeolite: Remarkably enhanced catalytic performance by fluorine
modification," Fuel Processing Technology, pp. 50-60, 2017.
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[5]
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A. Galadima and O.
Muraza, "Zeolite Catalysts in Upgrading of Bio-ethanol to Fuels Range
Hydrocarbons: A Review,," Journal of Industrial and Engineering
Chemistry, pp. 22-32, 2015.
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