A large petrochemical company considered, for many years
now from its crude oil whose petroleum production as well as refinery separation
the bottom residue has been combusting vacuum distillation as additional fuel
as well as land filling any balance. In environmental regulations due to recent
change, though, this option is no longer be available. Consequently, to convert
this crude oil vacuum residue into methyl-t-butyl ether (MTBE) the engineering
department division will be investigating. Oxygenated hydrocarbons are methyl-t-butyl
ether as a gasoline which is extremely valuable under the new air pollution
control regulations. To form carbon monoxide as well as hydrogen using partial
oxidation of the residue this is the first process.. (Huang, 2007)
1.1) Statements of problem of
Design Methanol and MTEB plant
In this project, synthesis the optimum flow sheet for the methanol
production process, and calculate the cost along with the cost of the
equipments with the manufacturing cost.
1.2). Background of Design
Methanol and MTEB plant
The desired reaction for the design plant of MTBE is given
below,
CH3OH + (CH3)2C=CH2 (CH3)3C-O-CH3
Must have 20% overload methanol in a feed stream.
There are two various feed sources
23% of isobutene
40% of isobutene
Now the background of Methanol plant design is that, Methanol
is clear, flammable liquid through the slightly alcoholic smell. Fuel ,Solvent along
with a feedstock on behalf of a manufacturing of different chemicals with the
adhesive foams as well as medicine.
1.3) Objective of Design
Methanol and MTEB plant
In the project design the objective of this project is that
to design the plant which produces the 100,000 metric ton/ year MTBE, along
with the analysis of the methanol synthesis.
2).Discussion of Design Methanol
and MTEB plant
On the final phase of production your general assignment
would focus, which includes the conversion of methanol as well as isobutylene
to MTBE. To an MTBE reactor methanol product must be fed in order to do this,
to form an MTBE where methanol as well as isobutylene is reacted with
conversion of single phase methanol 85.3%. In the MTBE separation column in
order to facilitate the removal of MTBE in an 8% molar excess methanol is fed.
In a stream of mixed hydrocarbons to the MTBE reactor the isobutylene feed; 30%
mole of the hydrocarbons stream in which isobutylene makes up. The average
molecular weight of hydrocarbons assumed to have 60. In a pressure distillation
column the product stream from MTBE reactor is then separated in the bottom
steam where 99% of MTBE is recovered. Liquid -0liquid extractor contains 5%
hydrocarbons, MTBE 1%, as well as 2% isobutylene fed to the extractor. Into the
organic stream 3 % of water absorbed.
In the flash drum water methanol extract stream is cooled.
Leaving vapor in flash drum contain the entering of water 2.5 percent as well
as entering of methanol 3.5%. In an atmospheric distillation column at last,
the methanol and water is separated; that contains 99% of methanol fed which is
combined with the fresh methanol to the MTBE reactor. In the liquid-liquid
extraction unit in order to make up the water lost as well as the flash drum to
this recycle stream a small stream of water is added. (Van-Dal & et.al, 2013)
2.1). Calculation of Design
Methanol and MTEB plant
Rate of reaction: of Design Methanol and MTEB plant
3). Conclusion of Design
Methanol and MTEB plant
In this study as we discuss in above it is possible to
generate 100,000 tons per year of MTBE at a conversion of 96 % with a purity
regarding 95 percent. The design of the selected parameter is shown in the flow
diagram. For the process the specification of the reactor needed such as
volume, height as well as diameter. To make methanol these intermediate products
are used upon the addition of isobutylene later it is transformed to
methyl-t-butyl ether.
4). Recommendations of Design Methanol and MTEB plant
For the MTBE plant design the 405 of the isobutene is chosen
to desire the original location for the production facility of MTBE. The profitability
metrics is greater even the revenues are the same. For the inability price of
the vacuum distillation the profitability is higher than the actual.
5). Attachments
Figure 1: Flow diagram (Methanol By partial
oxidation of vacuum distillation residue
Figure 2: Major Equipment Cost of Methanol plant design
Figure 3: Manufacturing Cost of Methanol plant
design
5.1) References of Design
Methanol and MTEB plant
Huang,
K. (2007). Design and Control of a Methyl Tertiary Butyl Ether (MTBE) DecompositionReactive
Distillation Column.
Van-Dal, S. É., & et.al. (2013). Design and simulation
of a methanol production plant from CO2 hydrogenation.