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Starting with reactant, hydrogen and oxygen gas and product water/water vapor whose properties dependent upon temperature, calculate the Gibb’s free energy 2H_2 (g)+O_2 (g)→ 2H_2 O (l)

Category: Accounting & Finance Paper Type: Coursework Writing Reference: APA Words: 2900

Part C

From the resistivity table below and from the ionic diffusivity parameters from the graph below, calculate the ohmic loss

For that case we have to know the values of each parameter 

Area=A=80 cm^2

j=0.9 A/cm^2 

lenght=0.004 cm

σ_i=0.15 ohm^(-1) cm^(-1)

σ_e=0.20 ohm^(-1) cm^(-1)

δ=0.005 cm 

In the first step we will calculate the value of current 

i=∫▒jds

i=j×A

i=0.9×80=72

Entropy 

Entropy ∆S is energy changes in chemical reactions that is related to the heat flow q_rev in the reaction. 

∆S^o   =  2 (69.9)-[ 2 (131)+1 (205)]= -327 J/(K mol)  

entropy =  ∆S  =q_rev/T

q_rev  =  n C_P  ∆T 

  ∆S  =  n C_P  ln⁡   T_2/T_1    

n_H=number of moles of hydrogen =2 

n_(O_2 )=number of moles of oxygen=1

n_(H_2 O )=number of moles of water =2

C_P=specific heat of capacity at constant pressure

specific heat of capacity of hydrogen at constant pressure= 14300 J/(kg K)

specific heat of capacity of oxygen at constant pressure= 913 J/(kg K)

specific heat of capacity of water vapour at constant pressure= 2020 K/(kg K)




 


Enthalpy 

∆H= ∫_(T_1)^(T_2)▒〖C_p  (T)dT〗

∆H_2  = ∆H_f +  nC_P  ∆T

∆H_f  = -241.826

Gibb’s free energy

G =  H-TS


 

Maximum efficiency for each temperature of operation 

Maximum efficiency is observed at 500 K.


B

Butler–Volmer equation for activation loss 

η_e  = -RT/(a n F) l n⁡〖i_0 〗+  RT/(a n F) l n⁡(i)

 R=gas constant=8.314 J/(mol K)

F =96485 C/mol

a_(H_2 O)  =1 

i_0= the exchange current density

i=1 amp

n=2 

Pb 2.5×10^(-13)

Zn 3.0×10^(-11)

Ag 4.0×10^(-7)

Ni 6.0×10^(-6)

Pt 5.0×10^(-4)

Pd 4.0×10^(-3)

T

Pb

Zn

Ag

Ni

Pt

Pd

300

0.52386654

0.313178

0.190413

0.155411

0.098244

0.249937

310

0.54132876

0.323618

0.19676

0.160591

0.101519

0.258268

320

0.55879098

0.334057

0.203108

0.165772

0.104794

0.266599

330

0.5762532

0.344496

0.209455

0.170952

0.108069

0.27493

340

0.59371542

0.354935

0.215802

0.176132

0.111343

0.283262

350

0.61117763

0.365375

0.222149

0.181313

0.114618

0.291593

360

0.62863985

0.375814

0.228496

0.186493

0.117893

0.299924

370

0.64610207

0.386253

0.234843

0.191673

0.121168

0.308255

380

0.66356429

0.396693

0.24119

0.196854

0.124443

0.316586

390

0.68102651

0.407132

0.247537

0.202034

0.127717

0.324918

400

0.69848873

0.417571

0.253884

0.207215

0.130992

0.333249

410

0.71595094

0.42801

0.260232

0.212395

0.134267

0.34158

420

0.73341316

0.43845

0.266579

0.217575

0.137542

0.349911

430

0.75087538

0.448889

0.272926

0.222756

0.140817

0.358243

440

0.7683376

0.459328

0.279273

0.227936

0.144091

0.366574

450

0.78579982

0.469768

0.28562

0.233116

0.147366

0.374905

460

0.80326203

0.480207

0.291967

0.238297

0.150641

0.383236

470

0.82072425

0.490646

0.298314

0.243477

0.153916

0.391567

480

0.83818647

0.501085

0.304661

0.248657

0.157191

0.399899

490

0.85564869

0.511525

0.311008

0.253838

0.160465

0.40823

500

0.87311091

0.521964

0.317356

0.259018

0.16374

0.416561

510

0.89057312

0.532403

0.323703

0.264199

0.167015

0.424892

520

0.90803534

0.542842

0.33005

0.269379

0.17029

0.433224

530

0.92549756

0.553282

0.336397

0.274559

0.173565

0.441555

540

0.94295978

0.563721

0.342744

0.27974

0.176839

0.449886

550

0.960422

0.57416

0.349091

0.28492

0.180114

0.458217

560

0.97788422

0.5846

0.355438

0.2901

0.183389

0.466548

570

0.99534643

0.595039

0.361785

0.295281

0.186664

0.47488

580

1.01280865

0.605478

0.368132

0.300461

0.189939

0.483211

590

1.03027087

0.615917

0.37448

0.305641

0.193213

0.491542

600

1.04773309

0.626357

0.380827

0.310822

0.196488

0.499873

610

1.06519531

0.636796

0.387174

0.316002

0.199763

0.508205

620

1.08265752

0.647235

0.393521

0.321183

0.203038

0.516536

630

1.10011974

0.657675

0.399868

0.326363

0.206313

0.524867

640

1.11758196

0.668114

0.406215

0.331543

0.209587

0.533198

650

1.13504418

0.678553

0.412562

0.336724

0.212862

0.541529

660

1.1525064

0.688992

0.418909

0.341904

0.216137

0.549861

670

1.16996861

0.699432

0.425256

0.347084

0.219412

0.558192

680

1.18743083

0.709871

0.431604

0.352265

0.222687

0.566523

690

1.20489305

0.72031

0.437951

0.357445

0.225962

0.574854

700

1.22235527

0.730749

0.444298

0.362625

0.229236

0.583186

710

1.23981749

0.741189

0.450645

0.367806

0.232511

0.591517

720

1.25727971

0.751628

0.456992

0.372986

0.235786

0.599848

730

1.27474192

0.762067

0.463339

0.378167

0.239061

0.608179

740

1.29220414

0.772507

0.469686

0.383347

0.242336

0.61651

750

1.30966636

0.782946

0.476033

0.388527

0.24561

0.624842

760

1.32712858

0.793385

0.48238

0.393708

0.248885

0.633173

770

1.3445908

0.803824

0.488728

0.398888

0.25216

0.641504

780

1.36205301

0.814264

0.495075

0.404068

0.255435

0.649835

790

1.37951523

0.824703

0.501422

0.409249

0.25871

0.658166

800

1.39697745

0.835142

0.507769

0.414429

0.261984

0.666498

810

1.41443967

0.845582

0.514116

0.419609

0.265259

0.674829

820

1.43190189

0.856021

0.520463

0.42479

0.268534

0.68316

830

1.4493641

0.86646

0.52681

0.42997

0.271809

0.691491

840

1.46682632

0.876899

0.533157

0.43515

0.275084

0.699823

850

1.48428854

0.887339

0.539504

0.440331

0.278358

0.708154

860

1.50175076

0.897778

0.545852

0.445511

0.281633

0.716485

870

1.51921298

0.908217

0.552199

0.450692

0.284908

0.724816

880

1.5366752

0.918656

0.558546

0.455872

0.288183

0.733147

890

1.55413741

0.929096

0.564893

0.461052

0.291458

0.741479

900

1.57159963

0.939535

0.57124

0.466233

0.294732

0.74981

910

1.58906185

0.949974

0.577587

0.471413

0.298007

0.758141

920

1.60652407

0.960414

0.583934

0.476593

0.301282

0.766472

930

1.62398629

0.970853

0.590281

0.481774

0.304557

0.774804

940

1.6414485

0.981292

0.596628

0.486954

0.307832

0.783135

950

1.65891072

0.991731

0.602976

0.492134

0.311106

0.791466

960

1.67637294

1.002171

0.609323

0.497315

0.314381

0.799797

970

1.69383516

1.01261

0.61567

0.502495

0.317656

0.808128

980

1.71129738

1.023049

0.622017

0.507676

0.320931

0.81646

990

1.72875959

1.033489

0.628364

0.512856

0.324206

0.824791

1000

1.74622181

1.043928

0.634711

0.518036

0.32748

0.833122

1010

1.76368403

1.054367

0.641058

0.523217

0.330755

0.841453

1020

1.78114625

1.064806

0.647405

0.528397

0.33403

0.849785

1030

1.79860847

1.075246

0.653752

0.533577

0.337305

0.858116

1040

1.81607069

1.085685

0.6601

0.538758

0.34058

0.866447

1050

1.8335329

1.096124

0.666447

0.543938

0.343854

0.874778

1060

1.85099512

1.106564

0.672794

0.549118

0.347129

0.883109

1070

1.86845734

1.117003

0.679141

0.554299

0.350404

0.891441

1080

1.88591956

1.127442

0.685488

0.559479

0.353679

0.899772

1090

1.90338178

1.137881

0.691835

0.56466

0.356954

0.908103

1100

1.92084399

1.148321

0.698182

0.56984

0.360228

0.916434

1110

1.93830621

1.15876

0.704529

0.57502

0.363503

0.924766

1120

1.95576843

1.169199

0.710876

0.580201

0.366778

0.933097

1130

1.97323065

1.179638

0.717224

0.585381

0.370053

0.941428

1140

1.99069287

1.190078

0.723571

0.590561

0.373328

0.949759

1150

2.00815508

1.200517

0.729918

0.595742

0.376603

0.95809

1160

2.0256173

1.210956

0.736265

0.600922

0.379877

0.966422

1170

2.04307952

1.221396

0.742612

0.606102

0.383152

0.974753

1180

2.06054174

1.231835

0.748959

0.611283

0.386427

0.983084

1190

2.07800396

1.242274

0.755306

0.616463

0.389702

0.991415

1200

2.09546618

1.252713

0.761653

0.621644

0.392977

0.999747

1210

2.11292839

1.263153

0.768

0.626824

0.396251

1.008078

1220

2.13039061

1.273592

0.774348

0.632004

0.399526

1.016409

1230

2.14785283

1.284031

0.780695

0.637185

0.402801

1.02474

1240

2.16531505

1.294471

0.787042

0.642365

0.406076

1.033071

1250

2.18277727

1.30491

0.793389

0.647545

0.409351

1.041403

1260

2.20023948

1.315349

0.799736

0.652726

0.412625

1.049734

1270

2.2177017

1.325788

0.806083

0.657906

0.4159

1.058065

1280

2.23516392

1.336228

0.81243

0.663086

0.419175

1.066396

1290

2.25262614

1.346667

0.818777

0.668267

0.42245

1.074728

1300

2.27008836

1.357106

0.825124

0.673447

0.425725

1.083059

1310

2.28755057

1.367545

0.831472

0.678628

0.428999

1.09139

1320

2.30501279

1.377985

0.837819

0.683808

0.432274

1.099721

1330

2.32247501

1.388424

0.844166

0.688988

0.435549

1.108052

1340

2.33993723

1.398863

0.850513

0.694169

0.438824

1.116384

1350

2.35739945

1.409303

0.85686

0.699349

0.442099

1.124715

1360

2.37486167

1.419742

0.863207

0.704529

0.445373

1.133046

1370

2.39232388

1.430181

0.869554

0.70971

0.448648

1.141377

1380

2.4097861

1.44062

0.875901

0.71489

0.451923

1.149709

1390

2.42724832

1.45106

0.882248

0.72007

0.455198

1.15804

1400

2.44471054

1.461499

0.888596

0.725251

0.458473

1.166371

1410

2.46217276

1.471938

0.894943

0.730431

0.461747

1.174702

1420

2.47963497

1.482378

0.90129

0.735612

0.465022

1.183033

1430

2.49709719

1.492817

0.907637

0.740792

0.468297

1.191365

1440

2.51455941

1.503256

0.913984

0.745972

0.471572

1.199696

1450

2.53202163

1.513695

0.920331

0.751153

0.474847

1.208027

1460

2.54948385

1.524135

0.926678

0.756333

0.478121

1.216358

1470

2.56694606

1.534574

0.933025

0.761513

0.481396

1.22469

1480

2.58440828

1.545013

0.939372

0.766694

0.484671

1.233021

1490

2.6018705

1.555452

0.94572

0.771874

0.487946

1.241352

1500

2.61933272

1.565892

0.952067

0.777054

0.491221

1.249683

1510

2.63679494

1.576331

0.958414

0.782235

0.494495

1.258014


Part C

From the resistivity table below and from the ionic diffusivity parameters from the graph below, calculate the ohmic loss

For that case we have to know the values of each parameter 

Area=A=80 cm^2

j=0.9 A/cm^2 

lenght=0.004 cm

σ_i=0.15 ohm^(-1) cm^(-1)

σ_e=0.20 ohm^(-1) cm^(-1)

δ=0.005 cm 

In the first step we will calculate the value of current 

i=∫▒jds

i=j×A

i=0.9×80=72


Ag

Ni

Pt

Pd

Pb

Zn

2.27E+03

5.16E+02

3.41E+02

3.61E+02

1.65E+02

6.11E+02

7.93E+03

1.80E+03

1.19E+03

1.26E+03

5.76E+02

2.14E+03

1.36E+04

3.09E+03

2.04E+03

2.17E+03

9.88E+02

3.67E+03

1.93E+04

4.38E+03

2.89E+03

3.07E+03

1.40E+03

5.19E+03

2.49E+04

5.67E+03

3.75E+03

3.97E+03

1.81E+03

6.72E+03

3.06E+04

6.96E+03

4.60E+03

4.88E+03

2.22E+03

8.25E+03

3.62E+04

8.25E+03

5.45E+03

5.78E+03

2.63E+03

9.78E+03

4.19E+04

9.54E+03

6.30E+03

6.68E+03

3.04E+03

1.13E+04

4.76E+04

1.08E+04

7.15E+03

7.59E+03

3.46E+03

1.28E+04

5.32E+04

1.21E+04

8.00E+03

8.49E+03

3.87E+03

1.44E+04

5.89E+04

1.34E+04

8.85E+03

9.39E+03

4.28E+03

1.59E+04

6.46E+04

1.47E+04

9.71E+03

1.03E+04

4.69E+03

1.74E+04

7.02E+04

1.60E+04

1.06E+04

1.12E+04

5.10E+03

1.89E+04

7.59E+04

1.73E+04

1.14E+04

1.21E+04

5.51E+03

2.05E+04

8.15E+04

1.86E+04

1.23E+04

1.30E+04

5.92E+03

2.20E+04

8.72E+04

1.99E+04

1.31E+04

1.39E+04

6.34E+03

2.35E+04

9.29E+04

2.11E+04

1.40E+04

1.48E+04

6.75E+03

2.51E+04

9.85E+04

2.24E+04

1.48E+04

1.57E+04

7.16E+03

2.66E+04

1.04E+05

2.37E+04

1.57E+04

1.66E+04

7.57E+03

2.81E+04

1.10E+05

2.50E+04

1.65E+04

1.75E+04

7.98E+03

2.96E+04

1.16E+05

2.63E+04

1.74E+04

1.84E+04

8.39E+03

3.12E+04

1.21E+05

2.76E+04

1.82E+04

1.93E+04

8.80E+03

3.27E+04

1.27E+05

2.89E+04

1.91E+04

2.02E+04

9.22E+03

3.42E+04

1.33E+05

3.02E+04

1.99E+04

2.11E+04

9.63E+03

3.58E+04

1.38E+05

3.15E+04

2.08E+04

2.20E+04

1.00E+04

3.73E+04

1.44E+05

3.27E+04

2.16E+04

2.29E+04

1.04E+04

3.88E+04

1.49E+05

3.40E+04

2.25E+04

2.38E+04

1.09E+04

4.03E+04

1.55E+05

3.53E+04

2.33E+04

2.47E+04

1.13E+04

4.19E+04

1.61E+05

3.66E+04

2.42E+04

2.56E+04

1.17E+04

4.34E+04

1.66E+05

3.79E+04

2.50E+04

2.65E+04

1.21E+04

4.49E+04

1.72E+05

3.92E+04

2.59E+04

2.75E+04

1.25E+04

4.64E+04

1.78E+05

4.05E+04

2.67E+04

2.84E+04

1.29E+04

4.80E+04

1.83E+05

4.18E+04

2.76E+04

2.93E+04

1.33E+04

4.95E+04

1.89E+05

4.31E+04

2.84E+04

3.02E+04

1.37E+04

5.10E+04

1.95E+05

4.43E+04

2.93E+04

3.11E+04

1.42E+04

5.26E+04

2.00E+05

4.56E+04

3.01E+04

3.20E+04

1.46E+04

5.41E+04

2.06E+05

4.69E+04

3.10E+04

3.29E+04

1.50E+04

5.56E+04

2.12E+05

4.82E+04

3.18E+04

3.38E+04

1.54E+04

5.71E+04

2.17E+05

4.95E+04

3.27E+04

3.47E+04

1.58E+04

5.87E+04

2.23E+05

5.08E+04

3.35E+04

3.56E+04

1.62E+04

6.02E+04

2.29E+05

5.21E+04

3.44E+04

3.65E+04

1.66E+04

6.17E+04

2.34E+05

5.34E+04

3.52E+04

3.74E+04

1.70E+04

6.33E+04

2.40E+05

5.47E+04

3.61E+04

3.83E+04

1.74E+04

6.48E+04

2.46E+05

5.59E+04

3.69E+04

3.92E+04

1.79E+04

6.63E+04

2.51E+05

5.72E+04

3.78E+04

4.01E+04

1.83E+04

6.78E+04

2.57E+05

5.85E+04

3.87E+04

4.10E+04

1.87E+04

6.94E+04

2.63E+05

5.98E+04

3.95E+04

4.19E+04

1.91E+04

7.09E+04

2.68E+05

6.11E+04

4.04E+04

4.28E+04

1.95E+04

7.24E+04

2.74E+05

6.24E+04

4.12E+04

4.37E+04

1.99E+04

7.39E+04


According to the given scenario Ag metal is the best one because it contain extremely low ohmic losses. It is use to this configuration. The electrical conductivity of silver is high due to this the resistivity loss of silver is low. This is because the voltages are directly proportional to the resistance.  This can be explained through the help of graph




Part D
Determine the concentration of losses using
η_conc=RT/ηF (1+1/α)  ln⁡(j_L/(j_l-j))
j_L=nF D^eff [(c_R^0)/δ]
For that case 
Part D
Determine the concentration of losses using
η_conc=RT/ηF (1+1/α)  ln⁡(j_L/(j_l-j))
j_L=nF D^eff [(c_R^0)/δ]
For that case 

B

J anode

j cathode

Concentration losses

0.06

10

1

0.143813746

0.07

12

2

0.047305898

0.08

14

3

0.033849603

0.09

16

4

0.028150761

0.1

18

5

0.024974423

0.11

20

6

0.022941915

0.12

22

7

0.021526895

0.13

24

8

0.020483836

0.14

26

9

0.019682489

0.15

28

10

0.019047219

0.16

30

11

0.018531049

0.17

32

12

0.018103236

0.18

34

13

0.017742806

0.19

36

14

0.017434952

0.2

38

15

0.017168919

0.21

40

16

0.016936703

0.22

42

17

0.016732225

0.23

44

18

0.016550784

0.24

46

19

0.016388686

0.25

48

20

0.016242987

0.26

50

21

0.016111314

0.27

52

22

0.015991731

0.28

54

23

0.015882643

0.29

56

24

0.015782724

0.3

58

25

0.015690863

0.31

60

26

0.015606122

0.32

62

27

0.015527703

0.33

64

28

0.015454922

0.34

66

29

0.015387192

0.35

68

30

0.015324004

0.36

70

31

0.015264916

0.37

72

32

0.01520954

0.38

74

33

0.015157538

0.39

76

34

0.015108609

0.4

78

35

0.015062489

0.41

80

36

0.015018943

0.42

82

37

0.01497776

0.43

84

38

0.014938753

0.44

86

39

0.014901755

0.45

88

40

0.014866613

0.46

90

41

0.014833191

0.47

92

42

0.014801367

0.48

94

43

0.014771027

0.49

96

44

0.014742071

0.5

98

45

0.014714405

0.51

100

46

0.014687946

0.52

102

47

0.014662616

0.53

104

48

0.014638345

0.54

106

49

0.014615066

0.55

108

50

0.014592721

0.56

110

51

0.014571255

0.57

112

52

0.014550616

0.58

114

53

0.014530757

0.59

116

54

0.014511636

0.6

118

55

0.014493212

0.61

120

56

0.014475447

0.62

122

57

0.014458307

0.63

124

58

0.014441759

0.64

126

59

0.014425772

0.65

128

60

0.01441032

0.66

130

61

0.014395376

0.67

132

62

0.014380914

0.68

134

63

0.014366912

0.69

136

64

0.014353349

0.7

138

65

0.014340203

0.71

140

66

0.014327457

0.72

142

67

0.014315091

0.73

144

68

0.01430309

0.74

146

69

0.014291437

0.75

148

70

0.014280118

0.76

150

71

0.014269118

0.77

152

72

0.014258424

0.78

154

73

0.014248023

0.79

156

74

0.014237904

0.8

158

75

0.014228055

0.81

160

76

0.014218466

0.82

162

77

0.014209126

0.83

164

78

0.014200025

0.84

166

79

0.014191156

0.85

168

80

0.014182508

0.86

170

81

0.014174074

0.87

172

82

0.014165846

0.88

174

83

0.014157817

0.89

176

84

0.014149979

0.9

178

85

0.014142326

0.91

180

86

0.01413485

0.92

182

87

0.014127547

0.93

184

88

0.01412041

0.94

186

89

0.014113433

0.95

188

90

0.014106612

0.96

190

91

0.014099941

0.97

192

92

0.014093415

0.98

194

93

0.014087029

0.99

196

94

0.014080779

1

198

95

0.014074662

1.01

200

96

0.014068671

1.02

202

97

0.014062804

1.03

204

98

0.014057057

1.04

206

99

0.014051427

1.05

208

100

0.014045909

1.06

210

101

0.0140405

1.07

212

102

0.014035198

1.08

214

103

0.014029998

1.09

216

104

0.014024899

1.1

218

105

0.014019896

1.11

220

106

0.014014989

1.12

222

107

0.014010173

1.13

224

108

0.014005446

1.14

226

109

0.014000806

1.15

228

110

0.013996251

1.16

230

111

0.013991777

1.17

232

112

0.013987384

1.18

234

113

0.013983068

1.19

236

114

0.013978829

1.2

238

115

0.013974663

1.21

240

116

0.013970568

1.22

242

117

0.013966544

1.23

244

118

0.013962588

1.24

246

119

0.013958699

1.25

248

120

0.013954874

1.26

250

121

0.013951113

1.27

252

122

0.013947414

1.28

254

123

0.013943774

1.29

256

124

0.013940194

1.3

258

125

0.01393667

1.31

260

126

0.013933203

temperature

E_thermal

n_act

n_ohmic

n_conc

V

300

143000

0.190413322

2.27E+03

0.143813746

1.41E+05

310

143000

0.196760433

7.93E+03

0.047305898

1.35E+05

320

143000

0.203107544

1.36E+04

0.033849603

1.29E+05

330

143000

0.209454654

1.93E+04

0.028150761

1.24E+05

340

143000

0.215801765

2.49E+04

0.024974423

1.18E+05

350

143000

0.222148876

3.06E+04

0.022941915

1.12E+05

360

143000

0.228495987

3.62E+04

0.021526895

1.07E+05

370

143000

0.234843097

4.19E+04

0.020483836

1.01E+05

380

143000

0.241190208

4.76E+04

0.019682489

9.54E+04

390

143000

0.247537319

5.32E+04

0.019047219

8.98E+04

400

143000

0.25388443

5.89E+04

0.018531049

8.41E+04

410

143000

0.26023154

6.46E+04

0.018103236

7.84E+04

420

143000

0.266578651

7.02E+04

0.017742806

7.28E+04

430

143000

0.272925762

7.59E+04

0.017434952

6.71E+04

440

143000

0.279272873

8.15E+04

0.017168919

6.15E+04

450

143000

0.285619983

8.72E+04

0.016936703

5.58E+04

460

143000

0.291967094

9.29E+04

0.016732225

5.01E+04

470

143000

0.298314205

9.85E+04

0.016550784

4.45E+04

480

143000

0.304661315

1.04E+05

0.016388686

3.88E+04

490

143000

0.311008426

1.10E+05

0.016242987

3.31E+04

500

143000

0.317355537

1.16E+05

0.016111314

2.75E+04

510

143000

0.323702648

1.21E+05

0.015991731

2.18E+04

520

143000

0.330049758

1.27E+05

0.015882643

1.62E+04

530

143000

0.336396869

1.33E+05

0.015782724

1.05E+04

540

143000

0.34274398

1.38E+05

0.015690863

4.83E+03

550

143000

0.349091091

1.44E+05

0.015606122

-8.34E+02

560

143000

0.355438201

1.49E+05

0.015527703

-6.50E+03

570

143000

0.361785312

1.55E+05

0.015454922

-1.22E+04

580

143000

0.368132423

1.61E+05

0.015387192

-1.78E+04

590

143000

0.374479534

1.66E+05

0.015324004

-2.35E+04

600

143000

0.380826644

1.72E+05

0.015264916

-2.91E+04

610

143000

0.387173755

1.78E+05

0.01520954

-3.48E+04

620

143000

0.393520866

1.83E+05

0.015157538

-4.05E+04

630

143000

0.399867977

1.89E+05

0.015108609

-4.61E+04

640

143000

0.406215087

1.95E+05

0.015062489

-5.18E+04

650

143000

0.412562198

2.00E+05

0.015018943

-5.75E+04

660

143000

0.418909309

2.06E+05

0.01497776

-6.31E+04

670

143000

0.425256419

2.12E+05

0.014938753

-6.88E+04

680

143000

0.43160353

2.17E+05

0.014901755

-7.45E+04

690

143000

0.437950641

2.23E+05

0.014866613

-8.01E+04

700

143000

0.444297752

2.29E+05

0.014833191

-8.58E+04

710

143000

0.450644862

2.34E+05

0.014801367

-9.14E+04

720

143000

0.456991973

2.40E+05

0.014771027

-9.71E+04

730

143000

0.463339084

2.46E+05

0.014742071

-1.03E+05

740

143000

0.469686195

2.51E+05

0.014714405

-1.08E+05

750

143000

0.476033305

2.57E+05

0.014687946

-1.14E+05

760

143000

0.482380416

2.63E+05

0.014662616

-1.20E+05

770

143000

0.488727527

2.68E+05

0.014638345

-1.25E+05

780

143000

0.495074638

2.74E+05

0.014615066

-1.31E+05

790

143000

0.501421748

2.80E+05

0.014592721

-1.37E+05

800

143000

0.507768859

2.85E+05

0.014571255

-1.42E+05

810

143000

0.51411597

2.91E+05

0.014550616

-1.48E+05

820

143000

0.520463081

2.97E+05

0.014530757

-1.54E+05

830

143000

0.526810191

3.02E+05

0.014511636

-1.59E+05

840

143000

0.533157302

3.08E+05

0.014493212

-1.65E+05

850

143000

0.539504413

3.14E+05

0.014475447

-1.71E+05

860

143000

0.545851524

3.19E+05

0.014458307

-1.76E+05

870

143000

0.552198634

3.25E+05

0.014441759

-1.82E+05

880

143000

0.558545745

3.31E+05

0.014425772

-1.88E+05

890

143000

0.564892856

3.36E+05

0.01441032

-1.93E+05

900

143000

0.571239966

3.42E+05

0.014395376

-1.99E+05

910

143000

0.577587077

3.48E+05

0.014380914

-2.05E+05

920

143000

0.583934188

3.53E+05

0.014366912

-2.10E+05

930

143000

0.590281299

3.59E+05

0.014353349

-2.16E+05

940

143000

0.596628409

3.65E+05

0.014340203

-2.22E+05

950

143000

0.60297552

3.70E+05

0.014327457

-2.27E+05

960

143000

0.609322631

3.76E+05

0.014315091

-2.33E+05

970

143000

0.615669742

3.82E+05

0.01430309

-2.39E+05

980

143000

0.622016852

3.87E+05

0.014291437

-2.44E+05

990

143000

0.628363963

3.93E+05

0.014280118

-2.50E+05

1000

143000

0.634711074

3.99E+05

0.014269118

-2.56E+05

1010

143000

0.641058185

4.04E+05

0.014258424

-2.61E+05

1020

143000

0.647405295

4.10E+05

0.014248023

-2.67E+05

1030

143000

0.653752406

4.16E+05

0.014237904

-2.73E+05

1040

143000

0.660099517

4.21E+05

0.014228055

-2.78E+05

1050

143000

0.666446628

4.27E+05

0.014218466

-2.84E+05

1060

143000

0.672793738

4.33E+05

0.014209126

-2.90E+05

1070

143000

0.679140849

4.38E+05

0.014200025

-2.95E+05

1080

143000

0.68548796

4.44E+05

0.014191156

-3.01E+05

1090

143000

0.691835071

4.50E+05

0.014182508

-3.07E+05

1100

143000

0.698182181

4.55E+05

0.014174074

-3.12E+05

1110

143000

0.704529292

4.61E+05

0.014165846

-3.18E+05

1120

143000

0.710876403

4.67E+05

0.014157817

-3.24E+05

1130

143000

0.717223513

4.72E+05

0.014149979

-3.29E+05

1140

143000

0.723570624

4.78E+05

0.014142326

-3.35E+05

1150

143000

0.729917735

4.84E+05

0.01413485

-3.41E+05

1160

143000

0.736264846

4.89E+05

0.014127547

-3.46E+05

1170

143000

0.742611956

4.95E+05

0.01412041

-3.52E+05

1180

143000

0.748959067

5.01E+05

0.014113433

-3.58E+05

1190

143000

0.755306178

5.06E+05

0.014106612

-3.63E+05

1200

143000

0.761653289

5.12E+05

0.014099941

-3.69E+05

1210

143000

0.768000399

5.18E+05

0.014093415

-3.75E+05

1220

143000

0.77434751

5.23E+05

0.014087029

-3.80E+05

1230

143000

0.780694621

5.29E+05

0.014080779

-3.86E+05

1240

143000

0.787041732

5.35E+05

0.014074662

-3.92E+05

1250

143000

0.793388842

5.40E+05

0.014068671

-3.97E+05

1260

143000

0.799735953

5.46E+05

0.014062804

-4.03E+05

1270

143000

0.806083064

5.52E+05

0.014057057

-4.09E+05

1280

143000

0.812430175

5.57E+05

0.014051427

-4.14E+05

1290

143000

0.818777285

5.63E+05

0.014045909

-4.20E+05

1300

143000

0.825124396

5.69E+05

0.0140405

-4.26E+05

1310

143000

0.831471507

5.74E+05

0.014035198

-4.31E+05

1320

143000

0.837818618

5.80E+05

0.014029998

-4.37E+05

1330

143000

0.844165728

5.86E+05

0.014024899

-4.43E+05

1340

143000

0.850512839

5.91E+05

0.014019896

-4.48E+05

1350

143000

0.85685995

5.97E+05

0.014014989

-4.54E+05

1360

143000

0.86320706

6.03E+05

0.014010173

-4.60E+05

1370

143000

0.869554171

6.08E+05

0.014005446

-4.65E+05

1380

143000

0.875901282

6.14E+05

0.014000806

-4.71E+05

1390

143000

0.882248393

6.20E+05

0.013996251

-4.77E+05

1400

143000

0.888595503

6.25E+05

0.013991777

-4.82E+05

1410

143000

0.894942614

6.31E+05

0.013987384

-4.88E+05

1420

143000

0.901289725

6.36E+05

0.013983068

-4.93E+05

1430

143000

0.907636836

6.42E+05

0.013978829

-4.99E+05

1440

143000

0.913983946

6.48E+05

0.013974663

-5.05E+05

1450

143000

0.920331057

6.53E+05

0.013970568

-5.10E+05

1460

143000

0.926678168

6.59E+05

0.013966544

-5.16E+05

1470

143000

0.933025279

6.65E+05

0.013962588

-5.22E+05

1480

143000

0.939372389

6.70E+05

0.013958699

-5.27E+05

1490

143000

0.9457195

6.76E+05

0.013954874

-5.33E+05

1500

143000

0.952066611

6.82E+05

0.013951113

-5.39E+05

























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