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Nomenclature (Naming) Rules The International Union of Pure and Applied Chemists (IUPAC) has designed a systematic naming system that avoids confusion among all the complex organic structures that are possible. Names are made up of a prefix (the stuff attached), a parent chain designating the longest carbon chain, and an ending (this defines a functional group—e.g. alkane, alcohol, etc).ALKANES:Rule #1- Find the longest continuous chain of carbons. If there is more than one possibility, choose the chain that is more branched. This is referenced to as the PARENT chain.IdentifylongestchainRule #2- Number the chain beginning at the end of the nearest substituent. If there are substituents equal distance from either end, look for the next nearest branch. Etc.Rule #3- Identify the substituents with a number and a name. If there is more than one substituent on the same carbon, they would each have the same number.Rule #4- Write the name for the molecule using hyphens between prefixes and commas between numbers. If there is more than one substituent with the same name, indicate the number of them using di, tri, tetra, etc. Prefixes are arranged in alphabetical order according to the substituent name.6-ethyl-3,4-dimethyloctane
Complex substituents- sometimes molecules have substituents (not part of the parent chain) that have additional branching. While there are some common names for 3- or 4-carbon complex side chains (e.g. Isobutyl), IUPAC has a systematic way of naming these groups as well. Basically, you follow similar rules as naming, but do it on a sub-part of the molecule. The main difference is that you always start numbering the side chain starting at the point of attachment as carbon number 1. Start at the point of attachment as number 1 and find the longest continuous carbon chain. This is the parent substituent. Number and name any branching groups according to this. All of the subname is enclosed in parentheses and placed into the full name of the molecule.When two chains of equal length compete for selection of the parent chain, choose the chain with the greater number of substituents. 2,3,5-Trimethyl-4-propylheptaneCycloalkanesAlkanes can be joined at the ends to make ring compounds. In order to do this, two hydrogens must be lost. Thus, the general formula for cycloalkanes is CnH2n. Cycloalkanes take precedent as the parent of the name if it is the same size or larger than any other alkyl chains in the molecule.Rule 1:Count the number of C's in the ring. If greater than or equal to the largest substituent chain, the ring is the parent. If a substituent is larger, that is the parent.Rule 2:for multi-substituted rings - start numbering at a point of attachment - number in the direction that gives the lowest numbers (sum the numbers to get a good idea). Substituents are numbered according to their alphabetical priority - halogens included.