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Organic molecular modeling lab

25/12/2020 Client: saad24vbs Deadline: 10 Days

Organic Chemistry


Molecular Model Lab


Objective: To employ molecular models to investigate the bonding of the carbon atom in various types of organic compounds. The geometry, bond flexibility / rotation, and the arrangement and / or connectivity of various atoms around the carbon will be explored.


Atoms: The following atoms will be used for this experiment:


Carbon = black ball


Hydrogen = white ball


Oxygen = red ball


Nitrogen = blue ball


Halogen (F, Cl, Br, or I) = green ball


Terminology:


Hybridization: The combination of atomic orbitals of different types. The hybridization depends on the electron geometry of a molecule


Isomer: Different compounds or representation of a compound with the same molecular formula


Constitutional (Structural)


Stereoisomers (Geometric or Optical)


Conformational


Sigma bond (σ): A bond where the electron density lies between two nuclei, along the axis joining them, and is cylindrically symmetric about the axis.


Pi bond (П): A bond formed between overlapping p orbitals.


Procedure:


Students will make models of the various organic compounds. Each group will collect 5 carbons, 12 hydrogens, 1oxygen, 3 halogens and 1nitrogen. For all of the compounds listed, use the math concept to determine the number of bonds required. Draw out these structures.


1. Compound # 1: CH4


· Replace one of the H with a halogen. What is the formula of this new compound? Are the compounds the same?


· Replace another H with a halogen. What is the new formula? Describe how this compound is similar and different from the other compounds.


· Replace another hydrogen with a halogen. What is the formula for the compound? Define the polarity of the above three compounds.


2. Compound #2: C2H6


· Rotate the C-C bonds 60º (6x).


· Replace one of the H with a halogen. What is the formula with the halogen added to the structure?


· Replace another H on the same C with another halogen. What is the formula?


· Replace an H on both carbons with a halogen? What is the formula?


· Rotate this model C-C bond by 60º (6x)


· Compare this model to the previous model where both halogens were bonded to the same carbon. How do these two di-halogen molecules compare and differ?


3. Compound # 3: C3H6O


· Bring these atoms together according to their bonding capabilities. How many compounds can be formed from these atoms? Discuss their similarities (besides formula) and differences


4. Compound #4: C4H10


· Connect the atoms in the molecule. Rotate the C2-C3 bonds 60º (6x).


· Discuss the impact on the rotation for this molecule. Are there any rotations which you feel are favored and disfavored by the molecule?


5. Compound #5: C4H8


· Connect the atoms in this molecule.


· How many different compounds can come from this formula? Describe the similarities and differences between these compounds.


6. Compound #6: C4H6


· Connect the atoms in this molecule.


· How many different compounds can come from this formula? Describe the similarities and differences between these compounds.


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